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When silica gel and anhydrous calcium chloride are placed in an atmosphere of high humidity, then which of them will have more moisture in the bulk?
Anhydrous calcium chloride and silica gel both are hygroscopic, but calcium chloride takes in more moisture because it absorbs moisture whereas silica gel adsorbs it.
Which of the following colloidal solutions is a positive sol?
Gelatin forms a lyophilic sol. However, in a strongly acidic medium, it forms a positively charged sol due to the selective adsorption of H+ ions from the medium.
Which of the following statements is not true?
The force of attraction between adsorbate and adsorbent molecules is fairly high, and adsorbate cannot be easily dislodged by change in temperature, pressure, etc. So, chemisorption is irreversible.
Plot of (x/m)2 against P gives a parabola with vertex at the origin. The value of n in Freundlich isotherm is
When a 5 g piece of charcoal is added to a 0.75 M CH3COOH, the concentration drops to 0.73 M. The extent of adsorption is
Number of moles of CH3COOH adsorbed = 0.75 - 0.73 = 0.02 Mass of CH3COOH adsorbed = 0.02 × 60 = 1.2 g x/m = 1.2/5 = 0.24
Choose incorrect statement about physical adsorption.
Only option 1 is incorrect. Since physical adsorption is an exothermic process, it occurs more readily at lower temperatures and decreases with increase in temperature (Le-Chatelier's Principle).
Which of the following catalysis can be explained by adsorption theory? a. Enzyme catalysis b. Acid-base catalysis c. Homogeneous catalysis d. Heterogeneous catalysis
Adsorption theory explains the mechanism of a reaction based on heterogeneous catalysis, where a solid catalyst is used and the reactants are in the gaseous state.
Which of the following characteristics is/are not correct for enzymes? a. Enzymes show maximum activity when pH is either very low or very high. b. Enzymes are normally heterogeneous catalysts that are very specific in action. c. Enzymes are specific biological catalysts that possess well-defined active sites. d. Chemically, all enzymes are globular proteins.
Statement 'a' is wrong as different enzymes are active at different pH values, but most enzymes function in pH around 7.4.
The term 'sorption' stands for
Sorption is the common term used for both absorption and adsorption. Absorption is the incorporation of a substance in one state into another of a different state (e.g., liquids being absorbed by a solid or gases being absorbed by water). Adsorption is the physical adherence or bonding of ions and molecules onto the surface of another molecule. The term 'sorption' is preferred when it is suspected that both processes are operative.
Under mild conditions of temperature and pressure, data and graphs for different physisorption and chemisorption processes are shown. Choose the one which is different from the others.
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