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p-Block Elements Test - 10
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p-Block Elements Test - 10
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  • Question 1/10
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    Gas 'X' is produced during the reaction of oxalic acid with hot concentrated H2SO4, passed over red hot carbon. The gas 'X' is

    Solutions

     

  • Question 2/10
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    The Ge (II) is a powerful reducing agent while Pb (IV) is a powerful oxidising agent. This is because

    Solutions

    Ge has an electronic configuration: [Ar], 3d10, 4s2, 4p2
    Pb has an electronic configuration: [Xe], 4f14, 5d10, 6s2, 6p2
    As is evident from the electronic configuration, the inert pair effect is more pronounced in Pb due to poor shielding by the d- and f-electrons, and hence the +4 oxidation state in lead is less stable and Pb (IV) is a powerful oxidising agent.
    On the other hand, Ge (II) is a strong reducing agent because it can easily be oxidised to Ge(IV).

     

  • Question 3/10
    1 / -0

    Which of the following oxides of Group 14 are amphoteric in nature?

    A. CO2
    B. SiO2
    C. SnO2
    D. PbO2

    Solutions

    SnO2 is amphoteric in nature.

    SnO2 + 4H+ → Sn+4 + 2H2O

    SnO2 + 2H2O + 2OH- → [Sn(OH)6]2-

    SiO2 is amphoteric in nature.

    2NaOH + SiO2 → Na2SiO3 + H2O

    4HF + SiO2 → SiF4 + 2H2O

     

  • Question 4/10
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    Which of the following pairs of compounds are incorrectly matched with their chemical formulae?

    (A) Butter of tin - SnCl4.5H2O (Stannic chloride)
    (B) Sugar of lead - 2PbCO3.Pb(OH)2 (Basic lead carbonate)
    (C) Carborundum - SiC (Silicon carbide)
    (D) Water glass - Na2SiO3 (Sodium silicate)
    (E) White lead - Pb(CH3COO)2 (Lead acetate)

    Solutions

    Sugar of lead is lead acetate, i.e. Pb(CH3COO)2.
    White lead is basic lead carbonate, i.e. 2PbCO3.Pb(OH)2.

     

  • Question 5/10
    1 / -0

    White metallic tin buttons get converted to grey powder. This transformation is related to

    Solutions

    At 13.2 °C (about 56 °F) or below, pure tin transforms from the silvery, ductile, metallic allotrope white α-tin to brittle, nonmetallic, β-form grey tin with a diamond cubic structure.

    Tin was the major metal used to make buttons in the French army's uniforms. When the Napoleon's army took on the Russian's, the severe Russian temperatures approached -30°C, which led to the disintegration of the crystalline form of tin causing fatal maladies in the soldiers.

     

  • Question 6/10
    1 / -0

    Consider the following statements:

    (A) Graphite is a good conductor of electricity due to the availability of delocalised electrons.
    (B) Carbon can form C=S bond because C has the ability to form dπ-dπ bond.
    (C) Both diamond and boron nitride have similar structures.
    (D) Silicon carbide has three-dimensional structures with each silicon and carbon being tetrahedrally surrounded by four atoms of the same kinds.

    Which of the given statements are incorrect?

    Solutions

    (B) Carbon does not form dπ-dπ bond because of the absence of d-orbital.
    (D) Silicon carbide has three-dimensional structures with each silicon and carbon being tetrahedrally surrounded by four atoms of the different kinds. In each case. carbon is tetrahedrally is surrounded by four silicon atoms and vice versa.

     

  • Question 7/10
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    Which of the following statements is incorrect?

    Solutions

    COCl2 is phosgene which is a toxic gas. Phosphine is PH3.

    Mellitic acid, also called graphitic acid or benzenehexacarboxylic acid, can be formed by reaction of graphite with hot and concentrated HNO3.
    C3O2 (carbon suboxide) is a foul-smelling lacrimatory (tear-stimulating) gas produced by the dehydration of malonic acid, CH2(COOH)2, with P4O10.

    CO is toxic because it has the ability to form a complex with haemoglobin in blood, and hence can deprive the body of oxygen.

     

  • Question 8/10
    1 / -0

    In the Serpeck's process of purification of bauxite, which one of the following is used to remove silicon dioxide?

    Solutions

    Bauxite, containing high percentage of silica, can be purified by Serpeck's process. In this process, finely powdered bauxite is mixed with coke and the mixture is heated to 1800°C in a current of nitrogen. The AlN thus obtained is reacted with hot and dilute NaOH, produced NaAlO2 and excess AlN is hydrolysed and Al(OH)3 is formed.

    Al2O3 + 3C + N2 → 3AlN + 3CO

    SiO+ 2C → Si­ + 2CO

    AlN + NaOH → NaAlO2 + NH3

    NaAlO2 + 2H2O → Al(OH)+ NaOH

    AlN + 3H2O → Al(OH)3 + NH3

     

  • Question 9/10
    1 / -0

    To prepare a silicon polymer containing 10 Si-O-Si linkages, the number of R2Si(OH)2 units required is

    Solutions

    To prepare a silicon polymer containing 'n' Si-O-Si linkages, the total number of chain-building units, R2Si(OH)2 required is (n - 1). Thus, the number of R2Si(OH)2 units needed is 9.

     

  • Question 10/10
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    [CaMg3O(Si4O11)] (Asbestos) is a special type of chain silicate in which two strands are cross-linked. The magnitude of charge on silicate anion is

    Solutions

     

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